Issue 20, 1996
From the journal:

Chemical Communications

Catalysed aerobic dehydrogenation of amines and an X-ray crystal structure of a bis(benzylamine) ruthenium(II) porphyrin species

Alan J. Bailey  and  Brian R. James  

Abstract

The complex trans-[RuVI(tmp)(O)2] 1 (tmp = dianion of 5,10,15,20-tetramesitylporphyrin) catalytically dehydrogenates primary and secondary amines in the presence of air; possible reaction steps involve a disproportionation reaction that generates a RuII intermediate, as evidenced by the isolated bis(benzylamine) complex [RuII(tmp)(PhCH2NH2)2] 2 which is characterised crystallographically.

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Article information

DOI
https://doi.org/10.1039/CC9960002343
Article type
Paper

Chem. Commun., 1996, 2343-2344

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Catalysed aerobic dehydrogenation of amines and an X-ray crystal structure of a bis(benzylamine) ruthenium(II) porphyrin species

A. J. Bailey and B. R. James, Chem. Commun., 1996, 2343 DOI: 10.1039/CC9960002343

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