Issue 21, 1996

NMR studies on ligand exchange at [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3] by para-hydrogen induced polarisation

Abstract

Enhancement of NMR signals by para-hydrogen induced polarisation allows the rapid characterisation of [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3]: these complexes undergo ligand exchange via a 16-electron complex, [IrH2Cl(PPh3)2], which has a square-based pyramidal structure.

Article information

Article type
Paper

Chem. Commun., 1996, 2395-2396

NMR studies on ligand exchange at [IrH2Cl(CO)(PPh3)2] and [IrH2Cl(PPh3)3] by para-hydrogen induced polarisation

C. J. Sleigh, S. B. Duckett and B. A. Messerle, Chem. Commun., 1996, 2395 DOI: 10.1039/CC9960002395

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