Issue 22, 1996

How strong is a π-facial hydrogen bond?

Abstract

Functional group substitutions (chemical mutations) in a molecular zipper complex have been used to construct a thermodynamic cycle for estimating the strength of a π-facial H-bond between an NH group and an aromatic ring resulting in a lower limit of –4.5 ± 0.5 kJ mol–1 for the magnitude of the intermolecular NH-π interaction in chloroform.

Article information

Article type
Paper

Chem. Commun., 1996, 2531-2532

How strong is a π-facial hydrogen bond?

H. Adams, K. D. M. Harris, G. A. Hembury, C. A. Hunter, D. Livingstone and J. F. McCabe, Chem. Commun., 1996, 2531 DOI: 10.1039/CC9960002531

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