Issue 24, 1996

First examples of metal and ligand accelerated catalysis of the Baylis–Hillman reaction

Abstract

Lanthanides and group III metal triflates (especially La, Sm) accelerate the Baylis–Hillman reaction (reaction between an unsaturated ester and aldehyde catalysed by DABCO, for example) and further acceleration can be obtained upon addition of diol ligands such as binol.

Article information

Article type
Paper

Chem. Commun., 1996, 2713-2714

First examples of metal and ligand accelerated catalysis of the Baylis–Hillman reaction

V. K. Aggarwal, G. J. Tarver and R. McCague, Chem. Commun., 1996, 2713 DOI: 10.1039/CC9960002713

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