Issue 49, 2020
From the journal:

Chemical Communications

Green synthesis of imine-based covalent organic frameworks in water†

Jesús Á. Martín-Illán,a   David Rodríguez-San-Miguel, ORCID logo ab   Carlos Franco,b   Inhar Imaz,c   Daniel Maspoch,cd   Josep Puigmartí-Luis ORCID logo *b  and  Félix Zamora ORCID logo *aefg  

* Corresponding authors

a Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain
E-mail: felix.zamora@uam.es
Tel: +34 91 4973962

b Department of Chemistry and Applied Biosciences, Institute for Chemical and Bioengineering, ETH Zurich, Vladimir Prelog Weg 1, 8093 Zurich, Switzerland

c Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST Campus UAB, Bellaterra, 08193 Barcelona, Spain

d ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain

e Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA-Nanociencia), Cantoblanco, Madrid E-28049, Spain

f Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, 28049 Madrid, Spain

g Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, 28049 Madrid, Spain

Abstract

Dynamic covalent bonds have been advantageously used to direct the synthesis of crystalline porous covalent organic frameworks (COFs). Unlike the standard synthetic protocols that involve harsh conditions, this work provides a high-yield “one-pot” green synthesis of imine-based COFs in water. Additionally, this aqueous synthesis can be performed under microwave conditions, considerably reducing the reaction time.

Graphical abstract: Green synthesis of imine-based covalent organic frameworks in water

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Article information

DOI
https://doi.org/10.1039/D0CC02033H
Article type
Communication
Submitted
18 Mar 2020
Accepted
11 May 2020
First published
11 May 2020

Chem. Commun., 2020,56, 6704-6707

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Green synthesis of imine-based covalent organic frameworks in water

J. Á. Martín-Illán, D. Rodríguez-San-Miguel, C. Franco, I. Imaz, D. Maspoch, J. Puigmartí-Luis and F. Zamora, Chem. Commun., 2020, 56, 6704 DOI: 10.1039/D0CC02033H

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