Antimonene nanosheets with enhanced electrochemical performance for energy storage applications

Abstract

Antimonene is an exfoliated 2D nanomaterial obtained from bulk antimony. It is a novel class of 2D material for energy storage applications. In the present work, antimonene was synthesized using a high-energy ball milling-sonochemical method. The structural, morphological, thermal, and electrochemical properties of antimonene were comparatively analyzed against bulk antimony. X-ray diffractometry (XRD) analysis confirms the crystal structure and 2D structure of antimonene, as a peak shift was observed. The Raman spectra show the peak shift for the E_g and A_1g modes of vibration of antimony, which confirms the formation of antimonene. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) images depict the exfoliation of antimonene from bulk antimony. Thermal analysis unveiled the thermal stability of antimonene up to 400 °C with only 3% weight loss. X-ray photoelectron spectroscopy (XPS) analysis reveals the formation of antimonene, which is free from contamination. The electrochemical properties of antimony and antimonene were investigated using cyclic voltammetry (CV) and chronopotentiometric (CP) analysis, using 2 M KOH as an electrolyte. Antimonene exhibited a relatively high specific capacitance of 597 F g⁻¹ compared to ball-milled antimony (101 F g⁻¹) at a scan rate of 10 mV s⁻¹. Moreover, electrochemical impedance spectroscopy (EIS) analysis revealed that antimonene has a relatively low equivalence series resistance (RESR) and low charge transfer resistance (RCT) compared to bulk antimony, which favors high electrochemical performance. The cyclic stability of antimonene was studied for 3000 cycles, and the results show high cyclic stability. The electrochemical results demonstrated that antimonene is a promising material for energy storage applications.