Ionic liquid assisted preparation and modulation of the photoluminescence kinetics for highly efficient CsPbX3 nanocrystals with improved stability

Abstract

CsPbX₃ (X = Cl, Br, I) nanocrystals (NCs) are competitive fluorescent materials for lighting and displays owing to their excellent photophysical properties. However, the stability and optoelectronic performance of the perovskite NCs are severely limited by the highly dynamic binding feature of the present ligand strategy. Herein, a facile approach was employed to synthesize CsPbBr₃ NCs with the assistance of the ionic liquid (IL) 1-butyl-3-methylimidazolium bromide ([Bmim]Br). By strictly controlling the addition dose of [Bmim]Br (n_IL/n_Pb = 0.125) into the reaction precursor, it is possible to obtain the desired cube-shaped and monodisperse CsPbBr₃ NCs with simultaneous enhancement of the storage and irradiation stability as well as photoluminescence quantum yields (PLQYs, ∼91%). Stability tests show that the emission intensity of the parent CsPbBr₃ NCs drops to 50% of its initial emission intensity after storage under an open atmosphere for 91 days, while the sample prepared with the assistance of [Bmim]Br can maintain 82% of the PL intensity. Meanwhile, the modified CsPbBr₃ NCs also present superior photo-stability, and still maintain 81% of the original PL intensity after continuous illumination under an ultraviolet lamp for 24 h, but the intensity of the parent CsPbBr₃ NCs reduces to 35% of the original intensity. Through the morphology, composition, and luminescence kinetics evolution of CsPbBr₃ NCs, these benefits were attributed to the modulation by [Bmim]Br, which could effectively provide Br ions for the formation and growth of NCs, resulting in the reduction of surface traps. Moreover, [Bmim]Br exhibited strong interactions with NCs, and the deprotonation of oleic acid (OA) was inhibited, resulting in the effective passivation of surface defects. Finally, CsPbX₃ NCs with different compositions were obtained via a facile anion exchange reaction, leading to the tunable emission in the range of 462–665 nm and a wide colour gamut (129.65% NTSC standard). This work opens a new avenue for modulating the surface properties of CsPbX₃ NCs, which will create opportunities for their application in the photoelectric field.