Periodic arrays of plasmonic crossed-bowtie nanostructures interspaced with plasmonic nanocrosses for highly sensitive LSPR based chemical and biological sensing

Abstract

In this paper, we present novel localized surface plasmon resonance (LSPR) sensors based on periodic arrays of gold crossed-bowtie nanostructures interspaced with gold nanocross pillars. Finite difference time domain (FDTD) numerical simulations were carried out to model bulk sensors as well as localized sensors based on the plasmonic nanostructures being proposed. The geometrical parameters of the plasmonic nanostructures are varied to obtain the best possible sensing performance in terms of sensitivity and figure of merit. A very high bulk sensitivity of 1753 nm per unit change in refractive index (nm RIU⁻¹), with a figure of merit for bulk sensing (FOM_bulk) of 3.65 RIU⁻¹, is obtained for these plasmonic nanostructures. This value of bulk sensitivity is higher in comparison to previously proposed LSPR sensors based on plasmonic nanopillars and nanocrosses. Moreover, the optimized LSPR sensors being proposed in this paper provide maximum sensitivity of localized refractive index sensing of 70 nm/nm with a FOM_localized of 0.33 nm⁻¹. This sensitivity of localized refractive index sensing is the highest reported thus far in comparison with previously reported LSPR sensors. It is also demonstrated that the operating resonance wavelengths of these LSPR sensors can be controllably tuned for specific applications by changing the dimensions of the plasmonic nanostructures.