Issue 3, 2021

Structure and dynamics of an aqueous solution containing poly-(acrylic acid) and non-ionic surfactant octaethylene glycol n-decyl ether (C10E8) aggregates and their complexes investigated by molecular dynamics simulations

Abstract

A detailed molecular dynamics simulation study of the self-assembly, intermolecular structure and thermodynamic behavior of an aqueous solution of non-ionic surfactant octa ethylene glycol n-decyl ether (C10E8) in the presence of a non-ionic polar polymer poly(acrylic acid) PAA is presented. The aggregation number Nagg and concentration of surfactant Cs in the simulation systems were varied in the range 0.01–0.32 M and 5 < Nagg < 101 (dilute to concentrated) with a dilute polymer concentration (Cp = 0.01 M). Lamellar aggregates of non-ionic surfactant in bulk aqueous solution are shown by molecular level computations for the first time. Spherical micellar aggregates and lamellar aggregates are formed at low and high Nagg, respectively. The transition from the spherical micelle phase to the lamellar phase in a binary solution is captured for the first time. A conformational transition from coiled to extended PAA chains adsorbed on the surfactant aggregate occurs at a particular value of Nagg, commensurate with the transition from spherical micelle aggregates to anisotropic lamellar aggregates. Formation of the surfactant aggregate in binary and ternary solutions and the polymer–surfactant complex in a ternary solution is enthalpically favored. Adsorption of PAA on the surfactant aggregate surface is driven by hydrogen bonds (HBs) between carboxylic acid groups of PAA and ethylene oxide groups of C10E8. A significant number of HBs occur between polar oxygens of C10E8 and hydroxyl oxygens of PAA. The results are in agreement with the limited available experimental data on this system.

Graphical abstract: Structure and dynamics of an aqueous solution containing poly-(acrylic acid) and non-ionic surfactant octaethylene glycol n-decyl ether (C10E8) aggregates and their complexes investigated by molecular dynamics simulations

Supplementary files

Article information

Article type
Paper
Submitted
20 Jul 2020
Accepted
02 Nov 2020
First published
20 Nov 2020

Soft Matter, 2021,17, 670-687

Structure and dynamics of an aqueous solution containing poly-(acrylic acid) and non-ionic surfactant octaethylene glycol n-decyl ether (C10E8) aggregates and their complexes investigated by molecular dynamics simulations

L. Kunche and U. Natarajan, Soft Matter, 2021, 17, 670 DOI: 10.1039/D0SM01322F

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