Encapsulation of lead halide perovskite nanocrystals (NCs) at the single-particle level: strategies and properties

Abstract

Lead halide perovskite NCs (APbX₃, A = formamidinium (FA), methylammonium (MA) or Cs; X = Cl, Br, I or their mixture) have attracted unprecedented attention due to their excellent photophysical properties and wide application prospects. However, the inherent ionic structure of APbX₃ NCs makes them very sensitive to external conditions such as water and oxygen, resulting in poor stability. As a feasible strategy, encapsulation is considered to be effective in improving the stability. In this minireview, we focus on single-particle-level coating, which not only can improve the stability but also maintain the nano effect of the original NCs. This review summarizes the fundamental information on APbX₃ NCs and the necessity of single-particle-level coating. Subsequently, a variety of heterostructures at the single-particle level are introduced in detail. Then, their applications are summarized. Moreover, we discuss the challenges and prospects of the single-particle-level heterostructures based on APbX₃ NCs.