Ce-hydroxamate metal–organic frameworks for photocatalytic H2 generation

Xuan Feng; Wenying Li; Lei Yang; Ting Song; Zhaoming Xia; Qiuxue Lai; Xuemei Zhou; Hai Xiao; Chong Liu

doi:10.1039/D2CC05189C

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Ce-hydroxamate metal–organic frameworks for photocatalytic H₂ generation†

Xuan Feng,^a Wenying Li,^b Lei Yang,^a Ting Song,^a Zhaoming Xia,

^b Qiuxue Lai,^a Xuemei Zhou,

*^a Hai Xiao

*^b and Chong Liu

*^a

Author affiliations

* Corresponding authors

^a School of Chemical Engineering, Sichuan University, Chengdu, China
E-mail: liuchong@scu.edu.cn, xuemeizhou@scu.edu.cn

^b Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: haixiao@tsinghua.edu.cn

Abstract

Exploring the rich coordination chemistry of Ce, here we report two new entries in the emerging category of hydroxamate-based metal–organic frameworks (MOFs). The two Ce-hydroxamate MOFs exhibited different band structures and photoelectrochemical properties based on their respective coordinative environments and overall structures, leading to varied H₂ generation performances.

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Article information

DOI: https://doi.org/10.1039/D2CC05189C
Article type: Communication
Submitted: 21 Sep 2022
Accepted: 08 Nov 2022
First published: 09 Nov 2022

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Chem. Commun., 2022,58, 13503-13506

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Ce-hydroxamate metal–organic frameworks for photocatalytic H₂ generation

X. Feng, W. Li, L. Yang, T. Song, Z. Xia, Q. Lai, X. Zhou, H. Xiao and C. Liu, Chem. Commun., 2022, 58, 13503 DOI: 10.1039/D2CC05189C

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Chemical Communications