SCHEDULED MAINTENANCE
The terdentate ligand 1,1,1-tris(diphenylphosphinomethyl)ethane (I) forms cobalt- and nickel-(I) complexes of general formula MLX (X = Cl, Br, or I). Spectral and magnetic data on the compounds are presented. They are non-electrolytes, are all isomorphous (X-rays) with the analogous Cu1 complexes, and probably have a pseudotetrahedral structure.
L. Sacconi and S. Midollini, J. Chem. Soc., Dalton Trans., 1972, 1213 DOI: 10.1039/DT9720001213
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