Oriented single-crystal Raman and i.r. spectra of vanadium(V) oxide are reported and absorption frequencies compared with those calculated using a simple transferred force field. It is shown that departures from previously established oxide-group frequencies are due to the relative lightness of the vanadium atom.
T. R. Gilson, O. F. Bizri and N. Cheetham, J. Chem. Soc., Dalton Trans., 1973, 291 DOI: 10.1039/DT9730000291
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