Issue 21, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

trans-Chlorotetrafluoro(trifluoromethyl)sulphur and its reactions with olefins and acetylenes

John I. Darragh,   Gerald Haran  and  David W. A. Sharp  

Abstract

trans-S(CF3)ClF4 has been prepared by the reaction between S(CF3)F3 and Cl2 in the presence of caesium fluoride. Its properties and addition reactions with olefins and acetylenes to give the compounds RCH2CH2Cl, RCH2CH(Cl)Me, RCF2CF2Cl, RCF(CF3)CF2Cl, RCF2CF(Cl)CF3, RCH2CF2Cl, RCF(H)CF2Cl, RCF2CFCl2, R(CF2CFCl)2 Cl, and RCH = CHCl [R =trans-S(CF3)F4] are described.

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Article information

DOI
https://doi.org/10.1039/DT9730002289
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 2289-2293

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trans-Chlorotetrafluoro(trifluoromethyl)sulphur and its reactions with olefins and acetylenes

J. I. Darragh, G. Haran and D. W. A. Sharp, J. Chem. Soc., Dalton Trans., 1973, 2289 DOI: 10.1039/DT9730002289

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