Issue 11, 1976

Oxidation of bis(perfluoroethyl) diselenide by antimony pentafluoride and by the dioxygen (1+) cation. Evidence for the novel cations [{Se(C2F5)}3]+ and [{Se(C2F5)}4n]2n+

Abstract

Bis(perfluoroethyl) diselenide is oxidized by both SbF5 and [O2][Sb2F11] to give orange or wine-red products, under appropriate conditions. These products are formulated as the [Sb2F11] salts of the cations [{Se(C2F5)}3]+ and [{Se(C2F5)}4n]2n+, where n is probably equal to 1.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 1006-1011

Oxidation of bis(perfluoroethyl) diselenide by antimony pentafluoride and by the dioxygen (1+) cation. Evidence for the novel cations [{Se(C2F5)}3]+ and [{Se(C2F5)}4n]2n+

J. Passmore, E. K. Richardson and P. Taylor, J. Chem. Soc., Dalton Trans., 1976, 1006 DOI: 10.1039/DT9760001006

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