Magnetic double-resonance measurements of rhodium, phosphorus, fluorine, and proton nuclear magnetic resonance parameters in some rhodium(I) and rhodium(III) compounds
Abstract
A number of related compounds containing rhodium–carbon bonds have been examined by 1H and 19F single-resonance and 1H-{19F}, 1H-{31P}, 1H-{103Rh}, 19F-{31P}, and 19F-{103Rh} double-resonance n.m.r. spectroscopy. Chemical shifts and signs and magnitudes of coupling constants involving these nuclei are presented and discussed.