Issue 7, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

Tertiary phosphine aluminohydride complexes of chromium-, molybdenum-, and tungsten-(II)

Andrew R. Barron,   Julian E. Salt  and  Geoffrey Wilkinson  

Abstract

The syntheses of the aluminohydride complexes [(dmpe)2HCr(µ-H)2AlH(µ-H)]2[dmpe = 1,2bis(dimethylphosphino)ethane], [(Me3P)4HM(µ-H)2AlH(µ-H)]2(M = Mo or W), and [(Me3P)4ClW(µ-H)2AlH(µ-H)]2 are reported. The 1H, 31P, and 27Al n.m.r. spectra are reported; all the molecules are non-rigid undergoing metal–hydride exchanges; the Al atoms are five-co-ordinate. The hydrolysis of aluminohydrides to give polyhydrides is discussed.

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Article information

DOI
https://doi.org/10.1039/DT9860001329
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 1329-1332

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Tertiary phosphine aluminohydride complexes of chromium-, molybdenum-, and tungsten-(II)

A. R. Barron, J. E. Salt and G. Wilkinson, J. Chem. Soc., Dalton Trans., 1986, 1329 DOI: 10.1039/DT9860001329

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