Issue 2, 1988

Tetragonal co-ordination polymers of rhodium(I) with stereochemically rigid aryl di-isocyanide linkages

Abstract

Tetragonal polymers of the type {[Rh(L)2]Cl}n with stacked layer (RhI⋯ RhI 3.31—3.41 Å) structures have been prepared by the reaction of [{Rh(CO)2Cl}2] with the polymerizing ligands (L) 1,4-di-isocyanobenzene, 1,4-di-isocyanonaphthalene, 4,4′-di-isocyanobiphenyl,2,4-di-isocyanotoluene, bis(4-isocyanophenyl)methane, or 1,5-di-isocyanonaphthalene. The new materials have been characterized by elemental analysis, thermal gravimetric analysis, i.r. and diffuse-reflectance spectra, as well as from their X-ray powder diffraction patterns.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1988, 469-476

Tetragonal co-ordination polymers of rhodium(I) with stereochemically rigid aryl di-isocyanide linkages

I. Feinstein-Jaffe, F. Frolow, L. Wackerle, A. Goldman and A. Efraty, J. Chem. Soc., Dalton Trans., 1988, 469 DOI: 10.1039/DT9880000469

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