The new phosphenium salt [P(NPri2)2][BPh4] has been identified in solution and observed to react with chlorinated solvents, including a facile oxidative addition of CH2Cl2 to the cation; in contrast, similar solutions of the [GaCl4]– salt are indefinitely stable indicating that the gallate anion suppresses the reactivity of the cation.
N. Burford, P. Losier, P. K. Bakshi and T. S. Cameron, J. Chem. Soc., Dalton Trans., 1993, 201 DOI: 10.1039/DT9930000201
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