Issue 12, 1996

Mode of formation of polymeric [{Ru(bipy)(CO)2}n](bipy = 2,2′-bipyridine) films

Abstract

Electrochemical generation of the organometallic polymer [{Ru0(bipy)(CO)2}n] by reduction of [RuII(trans-Cl2)(bipy)(CO)2] proceeded via the formation of the corresponding dimer [{RuI(trans-Cl)(bipy)(CO)2}2] and a tetrameric species; only dimers were formed by electroreduction of the [RuII(cis-Cl2)(bipy)(CO)2] isomer or [RuIICl(bipy){cis-(CO)2}(CO2Me)].

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 2581-2583

Mode of formation of polymeric [{Ru(bipy)(CO)2}n](bipy = 2,2′-bipyridine) films

S. Chardon-Noblat, A. Deronzier, D. Zsoldos, R. Ziessel, M. Haukka, T. Pakkanen and T. Venäläinen, J. Chem. Soc., Dalton Trans., 1996, 2581 DOI: 10.1039/DT9960002581

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements