Issue 13, 1996
From the journal:

Journal of the Chemical Society, Dalton Transactions

Guanidine anions as chelating ligands; syntheses and crystal structures of [Rh(η-C5Me5){η2-(NPh)2CNHPh}Cl] and [Ru(η-MeC6H4Pri-p)-{η2-(NPh)2CNHPh}Cl]

Philip J. Bailey,   Lindsey A. Mitchell  and  Simon Parsons  

Abstract

Treatment of the chloro-bridged dimers [{Rh(η-C5Me5)Cl2}2] and [{Ru(η-MeC6H4Pri-p)Cl2}2] with 1,2,3-triphenylguanidine in toluene solution led to the formation of [Rh(η-C5Me5){η2-(NPh)2CNHPh}Cl]1 and [Ru(η-MeC6H4Pri-p){η2-(NPh)2CNHPh}Cl]2 respectively. These represent the first examples of complexes containing guanidine anions as chelating ligands. Crystal structure analyses of both complexes have been performed.

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Article information

DOI
https://doi.org/10.1039/DT9960002839
Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 2839-2841

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Guanidine anions as chelating ligands; syntheses and crystal structures of [Rh(η-C5Me5){η2-(NPh)2CNHPh}Cl] and [Ru(η-MeC6H4Pri-p)-{η2-(NPh)2CNHPh}Cl]

P. J. Bailey, L. A. Mitchell and S. Parsons, J. Chem. Soc., Dalton Trans., 1996, 2839 DOI: 10.1039/DT9960002839

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