SCHEDULED MAINTENANCE
An X-ray crystallographic structure determination of a µ-azido azacryptate has confirmed the existence of collinear Cu–NNN–Cu geometry, earlier cited as the origin of unusual spectroscopy in dicopper µ-azido cryptates; the isoelectronic µ-cyanato cryptate is also isostructural.
C. J. Harding, F. E. Mabbs, E. J. L. MacInnes, V. McKee and J. Nelson, J. Chem. Soc., Dalton Trans., 1996, 3227 DOI: 10.1039/DT9960003227
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