A new platinum hydride was quantitatively formed in the reaction of trans-[PtH(Cl)(PPh3)2] with 5,11,17,23-tetra-tert-butyl-25,27-bis(diethylcarbamoylmethoxy)-26,28-bis(diphenylphosphinomethoxy)calix[4]arene; X-ray analysis and NMR studies showed that the hydrido ligand is directed into the hemispherical cavity induced around the platinum centre.
C. Wieser, D. Matt, L. Toupet, H. Bourgeois and J. Kintzinger, J. Chem. Soc., Dalton Trans., 1996, 4041 DOI: 10.1039/DT9960004041
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