Issue 23, 1996

Synthesis and structural characterisation of [Pd2(µ-Br)2(PBut3)2], an example of a palladium(I)–palladium(I) dimer

Abstract

The syntheses, spectroscopic characterisation and in one case (X = Br) the single-crystal structure of the novel PdI–PdI dimers [Pd2(µ-X)2(PBut3)2](X = Br or I) have been determined; preliminary results on their reactions with CO, H2, CNC6H3Me2 and C2H2 have also been obtained.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 4313-4314

Synthesis and structural characterisation of [Pd2(µ-Br)2(PBut3)2], an example of a palladium(I)–palladium(I) dimer

R. Vilar, D. M. P. Mingos and C. J. Cardin, J. Chem. Soc., Dalton Trans., 1996, 4313 DOI: 10.1039/DT9960004313

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