Heats of adsorption of water vapour on NaX and KNaX zeolites at different temperatures
Abstract
Differential heats of adsorption, qv, of different amounts of water vapour, ns, have been measured in a double calorimeter at 23, 40, 60 and 100°C on KNaX zeolite and at 100°C on NaX zeolite. The mechanism of successive filling of different energy sites in the cavities of KNaX zeolite by water molecules at 23°C was shown earlier by the wave-shaped change in qv, by the change in heat capacity and by the shift of band frequency in the i.r. spectrum of adsorbed water. The wave-shaped change in qv is replaced by a monotonic one as the temperature rises. At 100°C, qv smoothly decreases with increase in ns; the qv values for both zeolites are close. The differential heat capacities of adsorbed water, C, determined from the qv measurements at different temperatures and ns values, are close to those measured directly. The dependence of C on temperature has been estimated. The isotherms of water adsorption on these zeolites have also been considered.