The observation of circular dichroism (CD) in vibrational transitions in the infrared spectral region offers new possibilities for the determination of peptide solution conformation. Infrared or vibrational CD (VCD) is a particularly sensitive probe for the conformation of various peptide turns. Results of small linear and cyclic peptides containing β- or γ-turns are reported.
P. Xie, Q. Zhou and M. Diem, Faraday Discuss., 1994, 99, 233 DOI: 10.1039/FD9949900233
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