SCHEDULED MAINTENANCE
NN-Dimethylformamide azine, obtained as its hydrochloride by treating hydrazine or NN′-diacylhydrazines with thionyl chloride in dimethylformamide, undergoes transaminations with primary amines, giving 1,2,4-triazoles, and with secondary amines, giving other NN-disubstituted-formamide azines. The initial product of the reaction with aniline is a 1 : 1 adduct.
R. K. Bartlett and I. R. Humphrey, J. Chem. Soc. C, 1967, 1664 DOI: 10.1039/J39670001664
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