Issue 20, 1969

Cation-radicals: tris-(p-bromophenyl)amminium perchlorate and hexachloroantimonate

Abstract

Stable triarylamminium salts may be used as convenient one-electron oxidants for a range of organic molecules. Synthesis and characterisation of perchlorate and hexachloroantimonate salts of the tris-(p-bromophenyl)amminium cation [(p-BrC6H4)3N+] are described in detail. The hexachloroantimonate is easier to prepare and is much the more stable, both thermally and photochemically.

Article information

Article type
Paper

J. Chem. Soc. C, 1969, 2719-2720

Cation-radicals: tris-(p-bromophenyl)amminium perchlorate and hexachloroantimonate

F. A. Bell, A. Ledwith and D. C. Sherrington, J. Chem. Soc. C, 1969, 2719 DOI: 10.1039/J39690002719

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