Issue 2, 1993

Decamethylchromocenium tetracyanoethenide, (Cr(C5Me5)2]:.+[TCNE]˙+: a molecular ferromagnet with Tc= 3.65 K

Abstract

The electron-transfer salt 4[Cr(C5Me5)2]+[TCNE]˙(TCNE = tetracyanoethylene) has been prepared and structurally characterized by single-crystal X-ray diffraction. It possesses a solid-state motif of parallel 1D chains of alternating radical rations and anions similar to, but not isostructural to, the ferromagnet [Fe(C5Me5)2+[TCNE]˙·4[Cr(C5Me5)2]+[TCNE]˙ is a soft ferromagnet with no hysteretic effects observed and Tc= 3.65 K.

Article information

Article type
Paper

J. Mater. Chem., 1993,3, 215-218

Decamethylchromocenium tetracyanoethenide, (Cr(C5Me5)2]:.+[TCNE]˙+: a molecular ferromagnet with Tc= 3.65 K

J. S. Miller, R. S. Mclean, C. Vazquez, J. C. Calabrese, F. Zuo and A. J. Epstein, J. Mater. Chem., 1993, 3, 215 DOI: 10.1039/JM9930300215

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