Issue 0, 1972

Experiments on the synthesis of tetracycline. Part XI. Oxidation of ketone acetals and ethers by hydride transfer

Abstract

A method for oxidising a diol as its acetonide, or other acetal, by hydride transfer to the triphenyl carbonium ion, is described. Triphenylcarbonium ion oxidation is applied to the selective deprotection of benzyl and benzyloxy-carbonyl ethers.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1972, 542-552

Experiments on the synthesis of tetracycline. Part XI. Oxidation of ketone acetals and ethers by hydride transfer

D. H. R. Barton, P. D. Magnus, G. Smith, G. Streckert and D. Zurr, J. Chem. Soc., Perkin Trans. 1, 1972, 542 DOI: 10.1039/P19720000542

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