Issue 11, 1976
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Carbon-13 nuclear magnetic resonance assignments and biosynthesis of aflatoxin B1 and sterigmatocystin

Klaus G. R. Pachler,   Pieter S. Steyn,   Robert Vleggaar,   Philippus L. Wessels  and  De Buys Scott  

Abstract

The 13C n.m.r. spectra of two secondary fungal metabolites of related structure, aflatoxin B1 and sterigmatocystin, have been completely assigned. The distribution pattern of acetate units has been determined from 13C n.m.r. spectra of aflatoxin B1 derived from singly and doubly labelled [13C]acetate. These results and other published data on 13C-labelled sterigmatocystin agree with a biosynthetic scheme based on a C20 polyketide precursor.

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Article information

DOI
https://doi.org/10.1039/P19760001182
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1976, 1182-1189

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Carbon-13 nuclear magnetic resonance assignments and biosynthesis of aflatoxin B1 and sterigmatocystin

K. G. R. Pachler, P. S. Steyn, R. Vleggaar, P. L. Wessels and D. B. Scott, J. Chem. Soc., Perkin Trans. 1, 1976, 1182 DOI: 10.1039/P19760001182

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