Anions from α-Ph2P(O)-ketones do not give Horner–Wittig reactions but do react with alkyl halides, including α-halogenocarbonyl compounds, and Michael acceptors. The products may be stereoselectively reduced.
R. S. Torr and S. Warren, J. Chem. Soc., Perkin Trans. 1, 1983, 1173 DOI: 10.1039/P19830001173
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