By a combination of chemical degradations and 1H and 13C n.m.r. studies, the structure of the antibiotic lipiarmycin, produced by Actinoplanes deccanensis, has been elucidated. The molecule contains two glycosyl moieties, namely 2-O-methyl-4-O-homodichloro-orsellinate-β-D-rhamnose and 4-O-isobutyrate-5-methyl-β-rhamnose, attached to a 18-membered unsaturated lactone ring.
A. Arnone, G. Nasini and B. Cavalleri, J. Chem. Soc., Perkin Trans. 1, 1987, 1353 DOI: 10.1039/P19870001353
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...