Issue 3, 1989
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Intramolecular hydrogen abstraction. Hypervalent organoiodine compounds, convenient reagents for alkoxyl radical generation

Pedro de Armas,   José I. Concepción,   Cosme G. Francisco,   Rosendo Hernández,   José A. Salazar  and  Ernesto Suárez  

Abstract

The photolyses of 5α-cholestane-3β,6β-diol 3-acetate (1), 5α-cholestan-2β-ol (4), 5α-cholestan-4β-ol (8), (20R)-pregn-5-ene-3β,20-diol 3-acetate (19), (20S)-pregn-5-ene-3β,20-diol 3-acetate (21), and dihydrotigogenin 3-acetate (25) in the presence of iodine and various hypervalent organoiodine compounds lead to alkoxyl radicals which undergo intramolecular hydrogen abstraction to produce, in most cases, 1,4-iodohydrins and tetrahydrofuran derivatives.

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Article information

DOI
https://doi.org/10.1039/P19890000405
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1989, 405-411

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Intramolecular hydrogen abstraction. Hypervalent organoiodine compounds, convenient reagents for alkoxyl radical generation

P. de Armas, J. I. Concepción, C. G. Francisco, R. Hernández, J. A. Salazar and E. Suárez, J. Chem. Soc., Perkin Trans. 1, 1989, 405 DOI: 10.1039/P19890000405

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