SCHEDULED MAINTENANCE
Fused bicyclic oxonium ylides, generated with catalytic Rh2(OAc)4 from cyclic ethers bearing pendant diazo ketones, undergo a [1,2]- or [2,3]-shift to give O-bridged seven- or eight-membered carbocycles, in several cases with a high degree of stereoselectivity.
F. G. West, T. H. Eberlein and R. W. Tester, J. Chem. Soc., Perkin Trans. 1, 1993, 2857 DOI: 10.1039/P19930002857
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