Secondary benzylic and allylic diazoacetates undergo dirhodium(II)-catalysed diazo decomposition to form, competitively or exclusively, ketone and vinylidene products from intramolecular hydride abstraction in catalyst ligand-dependent molar ratios.
M. P. Doyle, A. B. Dyatkin and C. L. Autry, J. Chem. Soc., Perkin Trans. 1, 1995, 619 DOI: 10.1039/P19950000619
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