SCHEDULED MAINTENANCE
The treatment of α-(trifluoromethyl)styrene with organolithium reagents results in the selective formation of gem-difluoroalkenes in good-to-excellent yields. This reaction has been applied to the synthesis of 3-gem-difluoro-2-phenylallylic amines and other functionalised gem-difluoroalkenes.
J. Bégué, D. Bonnet-Delpon and M. H. Rock, J. Chem. Soc., Perkin Trans. 1, 1996, 1409 DOI: 10.1039/P19960001409
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