SCHEDULED MAINTENANCE
There is evidence of steric hindrance to the pyrolysis of di-t-alkyl carbonates. This may be estimated by using data from the unsymmetrical compounds. The relative rate data then show that the extent of charge production on the α-carbon atom is similar to that in acetates.
D. B. Bigley and C. M. Wren, J. Chem. Soc., Perkin Trans. 2, 1972, 2359 DOI: 10.1039/P29720002359
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