The rate constants have been measured for reaction of a series of 16 substituted thiophenoxides with 1-chloro-2,4-dinitrobenzene in 95%(v/v) ethanol–water at 25° using a stopped-flow spectrophotometric method. The values obtained which give a measure of the nucleophilic reactivities of the thiophenoxides correlate very well with the corresponding carbon basicities.
M. R. Crampton and M. J. Willison, J. Chem. Soc., Perkin Trans. 2, 1974, 238 DOI: 10.1039/P29740000238
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...