Issue 10, 1994

Synthesis of 2,6-diamidopyridine derivatives and their functions as flavin receptors in chloroform

Abstract

It has been found that 2,6-diamidopyridine derivatives act as flavin receptors by a triple hydrogen bond towards a uracil moiety of an isoalloxazine ring in CHCl3. The association constants were determined by 1H NMR (in CDCl3) and fluorescence (in CHCl3) spectroscopies; the largest is ca.103 mol–1 dm3. The triple hydrogen bond toward C(2)[double bond, length half m-dash]O, N(3)–H and C(4)[double bond, length half m-dash]O of the isoalloxazine ring was found to enhance slightly the oxidation activity in CHCl3.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1994, 2229-2237

Synthesis of 2,6-diamidopyridine derivatives and their functions as flavin receptors in chloroform

N. Tamura, K. Mitsui, T. Nabeshima and Y. Yano, J. Chem. Soc., Perkin Trans. 2, 1994, 2229 DOI: 10.1039/P29940002229

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