FeCl3 converts, in high yield, 3-butylsulfanyl-2,2′-bithiophene into a tris(butylsulfanyl)sexithiophene, which shows interesting optical properties and forms a stable radical cation and dication.
F. Goldoni, Chem. Commun., 1997, 2175 DOI: 10.1039/A705613C
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