Adamantane-like cages are formed when H2P(CH2)nPH2 (n = 2 or 3) react with acetylacetone or trifluoroacetylacetone and the crystal structures of the dichloropalladium(II) complexes of the C3-diphosphine ligands show that their cone angles are much larger than But2P(CH2)3PBut2; a diphospha-adamantane derived from o-C6H4(PH2)2 is also described.
V. Gee, A. Guy Orpen, H. Phetmung, P. G. Pringle and R. I. Pugh, Chem. Commun., 1999, 901 DOI: 10.1039/A902434D
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
