Polycondensation/pyrolysis of tris-s-triazine derivatives leading to graphite-like carbon nitrides

Tamikuni Komatsu; Takako Nakamura

doi:10.1039/B005982J

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Tamikuni Komatsu*^a and Takako Nakamura^b

Author affiliations

* Corresponding authors

^a National Institute of Materials and Chemical Research, High Density Energy Laboratory, 1-1 Higashi, Tsukuba-shi, Ibaraki, Japan
E-mail: BRA01367@nifty.ne.jp

^b National Institute of Materials and Chemical Research, Laser Reaction Group, 1-1 Higashi, Tsukuba-shi, Ibaraki, Japan

Abstract

Polycondensation/pyrolysis of 2,5,8-tricarbodiimide-tris-s-triazine and its derivatives gave hexagonal graphite-like pseudo carbon nitrides, CH_0.3–0.08N_1.0–0.63, composed of tris-s-triazine nuclei. The materials were stable up to 600–800 °C under an inert atmosphere depending on their nitrogen content.

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Article information

DOI: https://doi.org/10.1039/B005982J
Article type: Paper
Submitted: 25 Jul 2000
Accepted: 21 Sep 2000
First published: 15 Nov 2000

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J. Mater. Chem., 2001,11, 474-478

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