Issue 9, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Selectivity for dinegative versus mononegative oxoanionic guests within a cryptand host

Beatrice M. Maubert,b   Jane Nelson,ab   Vickie McKee,c   Raewyn M. Towna  and  Ibolya Pála  

a School of Chemistry, Queen’s University Belfast, UK

b Open University, Milton Keynes, UK

c Department of Chemistry, University of Loughborough, UK

Abstract

In the structures of three new oxoanion cryptates (M = Cr(VI), Se(VI) and SSO32−) of a protonated azacryptate host: H6L(MO42−)(ClO4)4 the dinegative anion invariably occupies the crypt, providing evidence of selectivity with respect to the mononegative analogue; solution studies support this observation.

Graphical abstract: Selectivity for dinegative versus mononegative oxoanionic guests within a cryptand host

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Article information

DOI
https://doi.org/10.1039/B101832I
Article type
Communication
Submitted
26 Feb 2001
Accepted
02 Mar 2001
First published
03 Apr 2001

J. Chem. Soc., Dalton Trans., 2001, 1395-1397

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Selectivity for dinegative versus mononegative oxoanionic guests within a cryptand host

B. M. Maubert, J. Nelson, V. McKee, R. M. Town and I. Pál, J. Chem. Soc., Dalton Trans., 2001, 1395 DOI: 10.1039/B101832I

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