Issue 22, 2001
From the journal:

Chemical Communications

The radical-chain addition of aldehydes to alkenes by the use of N-hydroxyphthalimide (NHPI) as a polarity-reversal catalyst

Shinya Tsujimoto,a   Takahiro Iwahama,a   Satoshi Sakaguchia  and  Yasutaka Ishii*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering & High Technology Research Center, Kansai University, Suita, Osaka, Japan.
E-mail: ishii@ipcku.kansai-u.ac.jp

Abstract

Hydroacylation of simple alkenes with aldehydes via a radical process was successfully achieved by the use of N-hydroxyphthalimide (NHPI) as a polarity-reversal catalyst. Thus, 5-tridecanone was obtained by the reaction of oct-1-ene with pentanal in the presence of small amounts of NHPI and dibenzoyl peroxide (BPO).

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Article information

DOI
https://doi.org/10.1039/B107548A
Article type
Communication
Submitted
20 Aug 2001
Accepted
03 Oct 2001
First published
26 Oct 2001

Chem. Commun., 2001, 2352-2353

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The radical-chain addition of aldehydes to alkenes by the use of N-hydroxyphthalimide (NHPI) as a polarity-reversal catalyst

S. Tsujimoto, T. Iwahama, S. Sakaguchi and Y. Ishii, Chem. Commun., 2001, 2352 DOI: 10.1039/B107548A

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