Issue 5, 2002
From the journal:

New Journal of Chemistry

Synthesis, photophysics, electrochemistry and binding studies of zinc(II) dithiolate crown complexes

Vivian Wing-Wah Yam,*a   Yung-Lin Pui,a   Kung-Kai Cheunga  and  Nianyong Zhua  

* Corresponding authors

a Department of Chemistry and Open Laboratory of Chemical Biology of The Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong SAR, People's Republic of China
E-mail: wwyam@hku.hk

Abstract

A series of zinc(II) dithiolate complexes containing ligands with benzo-15-crown-5 (dic), benzo-18-crown-6 (dic-18-6), 10-thiabenzo-15-crown-5 (dic-S), 10-selenabenzo-15-crown-5 (dic-Se) and 7,10,13-trithiabenzo-15-crown-5 (dic-3S) moieties have been synthesized and characterized, and their photophysics and electrochemistry studied. The metal ion-binding properties have been investigated by electronic absorption, emission and 1H NMR spectroscopy. The X-ray crystal structure of [Zn(SC6H4-CH3-p)2(dic-3S)] (5) has also been determined.

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Article information

DOI
https://doi.org/10.1039/B109497C
Article type
Paper
Submitted
11 Oct 2001
Accepted
08 Jan 2002
First published
23 May 2002

New J. Chem., 2002,26, 536-542

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Synthesis, photophysics, electrochemistry and binding studies of zinc(II) dithiolate crown complexes

V. Wing-Wah Yam, Y. Pui, K. Cheung and N. Zhu, New J. Chem., 2002, 26, 536 DOI: 10.1039/B109497C

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