Issue 22, 2003

Synthesis, characterisation and properties of bismuth(iii) ester pendant arm picket porphyrins

Abstract

A series of porphyrins bearing ester pendant arms has been synthesised. The number of potential coordinating groups was varied from one to four. In the case of the four-picket compounds, the arm length was also investigated. Structural properties towards the coordination of the bismuth(III) cation were studied. In the particular case of the two-picket molecules, the substitution isomers (5,10 or 5,15) were also prepared. An improvement of the rate of metallation was detected in the case of the single-picket porphyrin.

Graphical abstract: Synthesis, characterisation and properties of bismuth(iii) ester pendant arm picket porphyrins

Supplementary files

Article information

Article type
Paper
Submitted
28 Jul 2003
Accepted
08 Sep 2003
First published
19 Sep 2003

Dalton Trans., 2003, 4250-4254

Synthesis, characterisation and properties of bismuth(III) ester pendant arm picket porphyrins

Z. Halime, L. Michaudet, M. Razavet, C. Ruzié and B. Boitrel, Dalton Trans., 2003, 4250 DOI: 10.1039/B308776J

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