Synthesis, crystal structure and magnetic properties of two-dimensional malonato-bridged cobalt(ii) and nickel(ii) compounds

Abstract

Two isostructural malonato-bridged complexes of formula {[M(H₂O)₂][M(mal)₂(H₂O)₂]}_n [M = Co(II) (1), Ni(II) (2); H₂mal = malonic acid] have been synthesised and characterized by X-ray diffraction. Their structure consists of corrugated layers of trans-diaquabismalonatemetalate(II) and trans-diaquametal(II) units bridged by carboxylate–malonate groups in the anti–syn conformation. Two crystallographycally independent metal atoms occur in 1 and 2. The malonate anion acts simultaneously as a bidentate and bis-monodentate ligand. Variable-temperature (1.9–295 K) magnetic susceptibility measurements indicate the occurrence of weak antiferro- (1) and ferromagnetic (2) interactions between the cobalt(II) (1) and nickel(II) ions (2) through the anti–syn caboxylate–malonate bridge. A brief discussion on the structural diversity and crystal engineering possibilities of the malonate complexes with divalent first-row transition metal ions other than copper(II) is carried out.