Steric interactions in 1,3-dicarboxamidoanthraquinones have been employed to ‘twist’ isophthalamide-like anion binding sites; the crystal structure of the fluoride complex of a bis-3,5-dichlorophenylamide derivative shows the receptor acting as a ‘hydrogen-bonding corner’ in a ‘2 + 2’ fluoride containing molecular box.
S. J. Brooks, L. S. Evans, P. A. Gale, M. B. Hursthouse and M. E. Light, Chem. Commun., 2005, 734 DOI: 10.1039/B413654C
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