Issue 46, 2005
From the journal:

Chemical Communications

Chelated heteroatoms in polyoxometalates and the topological equivalence of {Coiii(en)} to type II cis-dioxometal centers. Synthesis and structure of [{Co(en)(μ-OH)2Co(en)}{PW10O37Co(en)}2]8− and [K⊂{Co(en)WO4}{WO(H2O)}(PW9O34)2]12−

Nebebech Belaia  and  Michael T. Pope*a  

* Corresponding authors

a Georgetown University, 37th & O St., N. W., Washington, USA
E-mail: popem@georgetown.edu

Abstract

The first examples of polyoxometalate structures that incorporate embedded chelated heteroatoms point to new possibilities for stereochemical control of applications.

Graphical abstract: Chelated heteroatoms in polyoxometalates and the topological equivalence of {Coiii(en)} to type II cis-dioxometal centers. Synthesis and structure of [{Co(en)(μ-OH)2Co(en)}{PW10O37Co(en)}2]8− and [K⊂{Co(en)WO4}{WO(H2O)}(PW9O34)2]12−

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Article information

DOI
https://doi.org/10.1039/B509756H
Article type
Communication
Submitted
11 Jul 2005
Accepted
18 Oct 2005
First published
31 Oct 2005

Chem. Commun., 2005, 5760-5762

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Chelated heteroatoms in polyoxometalates and the topological equivalence of {CoIII(en)} to type II cis-dioxometal centers. Synthesis and structure of [{Co(en)(μ-OH)2Co(en)}{PW10O37Co(en)}2]8− and [K⊂{Co(en)WO4}{WO(H2O)}(PW9O34)2]12−

N. Belai and M. T. Pope, Chem. Commun., 2005, 5760 DOI: 10.1039/B509756H

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